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  • 張國軍研究員

      

      

    張國軍,男,19647月生。工學博士,東華大學功能材料研究所研究員、博導。1987年至1996年在中國建筑材料科學研究院從事特種陶瓷的研究與開發工作,并于1995年獲中國建筑材料科學研究院博士學位。1996年至2005年在日本產業技術綜合研究所(AIST九州中心和中部中心)從事先進陶瓷的研究與開發工作。2005年獲中科院百人計劃資助回中國科學院上海硅酸鹽研究所工作,2016年起調入東華大學。中科院百人計劃、上海市浦江人才計劃獲得者。擔任Advances in Applied CeramicsJournal of the Asian Ceramic SocietiesJournal of Advanced CeramicsJournal of Ceramic Society of JapanChina’s Refractories編委會委員,中國硅酸鹽學會特陶分會理事等。

      


    主要研究方向:

    1. 微納結構可控的先進陶瓷材料的制備科學;

    2. 新型功能化結構陶瓷的性能發現與創制工藝;

    3. 極端環境(超高溫、強輻照、強腐蝕)下陶瓷材料的結構與性能演變;

    4. 環境功能材料的設計、制備與性能評價。

      

    主要研究成果:

    長期從事硼化物、氮化物、碳化物等非氧化物陶瓷的制備科學、微結構調控與性能表征研究,取得一系列研究成果,至今已發表SCI論文200余篇,其中在本領域權威期刊Journal of the American Ceramic Society上發表50余篇,Journal of the European Ceramic Society上發表20余篇,他人引用2000余次,申請專利20余項。深入研究了非氧化物陶瓷體系的相平衡關系、致密化和微結構調控以及強韌化機理,首次成功實現超高溫陶瓷的織構化,實現1600oC高溫強度無衰減,實現復相陶瓷體系里的殘余應力調控和材料可靠性提升;發展了陶瓷材料的原位反應合成工藝,探索出多個有實用價值的原位反應體系,成功實現復相陶瓷的微結構與性能調控。目前重點研究新型功能化結構陶瓷的性能發現與創制工藝、鋯化合物陶瓷的組分與微納結構設計以及相關制備科學,為先進結構陶瓷的功能化以及在超高溫、強輻照和強腐蝕等極端環境下的性能提升、演變機理、材料選擇和應用研究提供理論與實驗支持。

    榮譽及獲獎情況:

    1995年,陶瓷材料強度學及評價技術,國家科學技術進步二等獎。

    1996年,中國硅酸鹽學會第2屆青年科技獎。

    1997年,復相結構陶瓷顆粒尺寸效應,建材行業部級科學技術進步二等獎。

    2009年,中科院百人計劃結題優秀

      

    近年主持與承擔的項目:

    近年來負責完成了中國科學院百人計劃硼化物基陶瓷的制備科學與性能表征2005-2009、國家自然科學基金委重點項目超高溫陶瓷相圖、材料制備與微結構控制的研究2007-2010)、其他面上項目及國際合作項目,以及中科院及上海市科委的國際合作項目等多項課題。目前主要負責承擔國家自然科學基金委重點項目核能用鋯化合物陶瓷的協同設計、制備科學與相關機理研究、面上項目“ZrB2-SiC陶瓷的高溫強度、固溶行為、晶界結構及其相關性研究”、以及NSFC-JSPS合作項目“高強Zr(Hf)B2基超高溫陶瓷和MAX相材料的設計與先進制備工藝研究”等。

      

    近年代表性論文:

    1.Hu-Lin Liu, Guo-Jun Zhang, Ji-Xuan Liu, Hou-Zheng Wu, “Synergetic roles of ZrC and SiC in ternary ZrB2-SiC-ZrC ceramics”, Journal of the European Ceramic Society, 35: 4389-4397 (2015).

    2.Hu-Lin Liu, Ji-Xuan Liu, Hai-Tao Liu, Guo-Jun Zhang, “Contour maps of mechanical properties in ternary ZrB2-SiC-ZrC ceramic system”, ScriptaMaterialia, 107: 140-144 (2015).

    3.Hai-Bin Ma, Zhen-Yong Man, Ji-Xuan Liu, Fang-Fang Xu, Guo-Jun Zhang, “Microstructures, solid solution formation and high-temperature mechanical properties of ZrB2 ceramics doped with 5 vol.% WC”, Materials and Design, 81: 133-140 (2015).

    4.Ji-Xuan Liu, Guo-Jun Zhang, Fang-Fang Xu, Wen-Wen Wu, Hai-Tao Liu, Yoshio Sakka, Toshiyuki Nishimura, Tohru S. Suzuki, De-Wei Ni, Ji Zou, “Densification, microstructure evolution and mechanical properties of WC doped HfB2-SiC ceramics”, Journal of the European Ceramic Society, 35: 2707-2714 (2015).

    5.Fei Li, Meng-Shi Liang, Xi-Fei Ma, Xiao Huang, Guo-Jun Zhang, “Preparation and characterization of stoichiometric zirconium carbide foams by direct foaming of zirconia sols”,Journal of Porous Materials, 22: 493-500 (2015).

    6.Xin-Gang Wang, Guo-Jun Zhang, Jian Zhao, Jia-Xiang Xue, Chang-ming Xu, and Pei-ling Wang, “High-strength ZrC ceramics doped with Aluminum”, Journal of the American Ceramic Society, 97 (11): 3367-3370 (2014).

    7.Yun Tang, Jia-Xiang Xue, Guo-Jun Zhang, Xin-Gang Wang and Chang-Ming Xu, “Microstructural differences and formation mechanisms of spark plasma sintered ceramics with or without boron nitride wrapping”, ScriptaMaterialia,75: 98-101 (2014).

    8.Jia-Xiang Xue, Guo-Jun Zhang, Li-Ping Guo, Hai-Bin Zhang, Xin-Gang Wang, Ji Zou, Shu-Ming Peng, Xing-Gui Long, “Improved radiation damage tolerance of titanium nitride ceramics by introduction of vacancy defects”, Journal of the European Ceramic Society,34: 633-639 (2014).

    9.Liu J. X., Huang X., Zhang G. J., “Pressureless sintering of hafnium carbide-silicon carbide ceramics”, J. Am. Ceram. Soc., 96 (6): 1751-1756 (2013).

    10.Sun S. K., Zhang G. J., Liu J. X., Zou J., Ni D. W., “Reaction sintering of HfC/W cermets with high strength and toughness”, J. Am. Ceram. Soc., 96 (3): 867-872 (2013).

    11.Sun S. K., Zhang G. J., Wu W. W., Liu J. X., Suzuki T., Sakka Y., “Reactive spark sintering of ZrC and HfC ceramics with fine microstructures”, Scripta Mater., 69: 139-142 (2013).

    12.Xie B. H., Huang X., Zhang G. J.,” High thermal conductive polyvinyl alcohol composites with hexagonal boron nitride microplatelets as fillers”, Composites Sci. Tech., 85: 98-103 (2013).

    13.Xue J. X., Zhang G. J., Xu F. F., Zhang H. B., Wang X. G., Peng S. M., Long X. G., “Lattice expansion and microstructure evaluation of Ar ion-irradiated titanium nitride”, Nuclear Instruments and Methods in Physics Research B, 308: 62-67 (2013).

    14.Wang X. G., Zhang G. J., Xue J. X., Tang Y., Huang X., Xu C. M., Wang P. L., “Reactive Hot Pressing of ZrC-SiC Ceramics at Low Temperature”, J. Am. Ceram. Soc., 96 (1): 32-36 (2013).

    15.Tang Y., Zhang G. J., Xue J. X., Wang X. G., Xu C. M., Huang X., “Densification and mechanical properties of hot-pressed ZrN ceramics doped with Zr or Ti”, J. Eur. Ceram. Soc., 33 (7): 1363-1371 (2013).

    16.Hui-Yu Qiu, Wei-Ming Guo, Ji Zou and Guo-Jun Zhang, “ZrB2 powders prepared by boro/carbothermal reduction of ZrO2: the effects of carbon source and reaction atmosphere”, Powder Technology, 217: 462-466 (2012).

    17.Zou J., Zhang G. J., Hu C. F., Nishimura T., Sakka Y., Vleugels J., Biest O., Strong ZrB2-SiC-WC Ceramics at 1600 degrees C, J. Am. Ceram. Soc., 95 (3): 874-878 (2012).

    18.Wang X. G., Liu J. X., Kan Y. M., Zhang G. J., Effect of solid solution formation on densification of hot-pressed ZrC ceramics with MC (M = V, Nb, and Ta) additions, J. Eur. Ceram. Soc., 32 (8): 1795-1802 (2012).

    19.Liu H. T., Zou J., Ni D. W., Liu J. X., Zhang G. J., Anisotropy oxidation of textured ZrB2-MoSi2 ceramics, J. Eur. Ceram. Soc., 32 (12): 3469-3476 (2012).

    20.De-Wei Ni, Guo-Jun Zhang, Yan-Mei Kan and Yoshio Sakka“Textured h-BN Ceramics Prepared by Slip Casting”, J. Am. Ceram. Soc., 94(5): 1397-1404 (2011).

    21.Ji Zou, Shi-Kuan Sun, Guo-Jun Zhang, Yan-Mei Kan, Pei-Ling Wang and TatsukiOhji,“Chemical Reactions, Anisotropic Grain Growth and Sintering Mechanisms of Self-Reinforced ZrB2–SiC Doped with WC”, J. Am. Ceram. Soc., 94(5): 1575-1583 (2011).

    22.Wei-Ming Guo, Zhen-Guo Yang andGuo-Jun Zhang, “New Borothermal Reduction Route to Synthesize Submicrometric ZrB2 Powders with Low Oxygen Content”, J. Am. Ceram. Soc., 94(11): 3702-3705 (2011).

    23.Ji Zou, Guo-Jun Zhang, Shi-Kuan Sun, Hai-Tao Liu, Yan-Mei Kan, Ji-Xuan Liu and Chang-Ming Xu,“ZrO2 removing reactions of Groups IV–VI transition metal carbides in ZrB2 based composites”, J. Eur. Ceram. Soc., 31(3): 421-427 (2011).

    24.Xin-Gang WangWei-Ming GuoYan-Mei KanGuo-Jun Zhang and Pei-Ling Wang“Densification behavior and properties of hot-pressed ZrC ceramics with Zr and graphite additives”, J. Eur. Ceram. Soc., 31(6): 1103-1111 (2011).

    25.Hai-Tao Liu, Ji Zou, De-Wei Ni, Wen-Wen Wu, and Guo-Jun Zhang, “Textured and platelet-reinforced ZrB2-based ultra-high-temperature ceramics”, Scripta Materialia, 65(1): 37- 40 (2011).

    26.Bo Yuan and Guo-Jun Zhang, “Microstructure and shear strength of self-joined ZrB2 and ZrB2-SiC with pure Ni”, Scripta Materialia, 64: 17-20 (2011).

    27.Jia-Xiang Xue, Ji-Xuan Liu, Bin-HuanXie and Guo-Jun Zhang, “Pressure-induced preferential grain growth, texture development and anisotropic properties of hot pressed hexagonal boron nitride ceramics”, Scripta Materialia, 65: 966-969 (2011).

    28.Ji-Xuan Liu, Yan-Mei Kan and Guo-Jun Zhang, “Pressureless sintering of tantalum carbide ceramics without additives”, J. Am. Ceram. Soc., 93: 370-373 (2010).

    29.Ji-Xuan Liu, Yan-Mei Kan and Guo-Jun Zhang, “Synthesis of ultra-fine hafnium carbide powder and its pressureless sintering”J. Am. Ceram. Soc., 93: 980-986 (2010).

    30.Ji Zou, Guo-Jun Zhang and Yan-Mei Kan, “Pressureless densification and mechanical properties of hafnium diboride doped with B4C: From solid state sintering to liquid phase sintering”,J. Eur. Ceram. Soc.,30: 2699-2705 (2010).

    31.Ji-Xuan Liu, Bo-Yuan, Yan-Mei Kan, Guo-Jun Zhang and Pei-Ling Wang, “Properties of porous Si3N4/BN composites fabricated by RBSN technique”, Int. J. Appl. Ceram. Technol., 7: 536-545 (2010).

      

    近年主要邀請報告:

    1. Reactive Processes for Diboride-based Ultra High Temperature Ceramics, The 11th Pacific Rim Conference on Ceramic Societies (PacRim 11), Jeju, Korea, 2015.8.

    2. Recent Advances on Reactive Synthesis of Non-Oxide Ceramics, 4th International Symposium on SiAlONs and Non-Oxides (ISSNOX 4), Nagahama, Japan, 2014.5.

    3. High Performance HfB2-SiC Ceramics Doped with WC: Densification Mechanism, Microstructure Evolution and Mechanical Properties, The 10th Pac Rim Conference on Ceramic and Glass Technology (PacRim 10), San Diego, USA, 2013.6.

    4. Zirconium-Based Non-Oxide Ceramics: Preparation, Microstructure Tailoring and Properties (Keynote), 13th International Conference of the European Ceramic Society, Limoges, France, 2013.6.

    5. Non-Oxides of Zirconium: Recent Progress on the Preparation, Microstructure Tailoring and Properties, 8th International Conference on High Temperature Ceramics Matrix Composites (HTCMC-8), Xi'an, China, 2013.9.

    6. High-Temperature Bending Strength of ZrB2-20vol%SiC Ceramics, 36th International Conference and Exposition on Advanced Ceramics and Composites, Daytona Beach, USA, 2012.1.

    7. Texturing Technologies for Group IVB Metal Diboride Ceramics, 36th International Conference and Exposition on Advanced Ceramics and Composites, Daytona Beach, USA, 2012.1.

    8. Oxidation Behavior and Microstructure Stability of ZrB2-SiC and ZrB2-MoSi2 Ultra High Temperature Ceramics, International Symposium on New Frontier of Advanced Si-Based Ceramics and Composites (ISASC2012), Soul, Korea, 2012.3.

    9. Textured Diboride Based UHTCs with Anisotropic Properties, Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications II, Hernstein, Germany, 2012.5.

    10. Strong Diboride-Based Ultra-high Temperature Ceramics at 1600?C, International Conference on the Science and Technology for Advanced Ceramics (STAC-6), Yokohama, Japan, 2012.6.

    11. Advanced Zirconium-based Non-oxide Ceramics: Preparation, Microstructure Tailoring and Properties, 3rd International Symposium on Advanced Ceramics and Technology for Sustainable Energy Applications (ACTSEA 3), Taiwan, 2011.10.

    12. Group IVB Metal Diboride Ceramic Composites: Improvement of Material Properties through Microstructure Tailoring, 17th International Symposium on Boron, Borides and Related Materials (ISBB2011), Istanbul, Turky, 2011.9.

    13. Non-Oxide Ceramics for Extreme Environment Applications, The 9th International Meeting of Pacific Rim Ceramic Societies (PacRim 9), Cairns, Australia, 2011.7.

    14. Material Properties Improvement in Ultra High Temperature Ceramics via Microstructure Tailoring, CIMTEC 2010, Monticatini, Italy, 2010. 6.

    15. High Temperature Stability of ZrB2 Based Ultra High Temperature Ceramics, The 3rd International Congress on Ceramics (ICC3), Osaka Japan, 2010. 11.

    16. Processing and Microstructure Tailoring of Ultra High Temperature Ceramics, the 3rd International Symposium on SiAlONs and Non-Oxides (ISSNOX 3), Cappadocia, Turkey, 2010.6.

    17. High Temperature Stabilized Silicon Nitride by Hexagonal Boron Nitride Nanocoating, International Symposium on Advanced Ceramics and Technology for Sustainable Energy Applications (ACTSEA-2), Grand Hotel, Taipei, Taiwan, 2009.11.

    18. Densification and Properties of ZrB2-SiC Ultra-High Temperature Ceramics with Carbide Addition, 2nd International Congress on Ceramics (ICC2), Verona, Italy, 2008.6.

    19. Ultra-High Temperature Ceramics (UHTCs) Based on ZrB2 and HfB2 Systems, 16th International Symposium on Boron, Borides and Related Materials (ISBB2008), Matsue, Shimane, Japan, 2008.9.

    20. Reactive Processing of Boride Ceramic Composites, 2nd Int. Symposium on Sialons and Non-Oxides (ISSNOX-2), Mie, Japan, 2007.12

    21. Ultra-High Temperature Ceramics (UHTCs) Based on ZrB2-SiC System, 7th Pacific Rim Conference on Ceramic and Glass Technology, Shanghai, China, 2007.11

      

    國際交流與合作:

    與日本物質材料研究機構、意大利陶瓷科學技術研究所、比利時魯汶大學等建立了良好的合作研究關系,每年派遣青年教師、研究生赴國外研究機構開展合作研究,同時也為研究生畢業后順利聯系國外博士后創造條件。每年與國外同行科學家共同組織研討會,為合作項目的順利開展提供有效的學術交流平臺,為研究生參與國際學術交流創造更多機會。

      

    課題組主要儀器設備:

    1. 材料制備設備:放電等離子燒結設備(Spark Plasma Sintering,德國FCT)、熱壓燒結爐、無壓燒結爐、以及其他常規工藝設備。

    2. 分析測試儀器設備:掃描電鏡(配備能譜儀)、力學性能測試系統(彎曲強度、硬度、彈性模量)、激光熱導儀、差熱/熱重分析儀等。

    歡迎具有材料、物理、化學等專業背景的同學加入我們的研究團隊!

    聯系電話:021-67874093                                                                                    Emailgjzhang@dhu.edu.cn  

      

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